Journal of Oil, Gas and Petrochemical Technology

Journal of Oil, Gas and Petrochemical Technology

Effectiveness of Sol-Gel Organically Modified Silica Xerogel as a Barrier Coating for Corrosion Protection

Document Type : Research Paper

Authors
Faculty of Chemical Engineering, Tarbiat Modares University, Tehran, Iran
Abstract
Metal Alloys have a vital role in many technological and industrial applications; however, the vulnerability of alloys to corrosion inevitably has disruptive issues on huge economic losses and catastrophes. In this study, the green method was used to obtain an eco-friendly coating of a silica xerogel by various acidic and basic catalysts. Tetraethoxysilane (TEOS) as a precursor and organic solvent was then applied to carbon steel via the dip-coating method. Prepared coated specimens were characterized with infrared spectroscopy analysis by fourier transform (FT-IR), X-ray Spectroscopy (EDS), scanning electron microscopy in type of electrone microscopy (FE-SEM), Optical Microscope (OM), and gravimetric analysis. The corrosion rate was used to evaluate the corrosion resistance. This research was conducted to achieve the optimized parameters for an efficient corrosion protective coating, herein by comparison of the results, we concluded the 100-200 percent improvement of corrosion resistance against bare specimens for the same period of immersion in NaCl solution. The specimens with optimized parameters presented the ascending corrosion resistance from 0.274 mm/yr to 0.124 mm/yr which confirmed the suitability of the protective coating for relative applications.
Keywords

  1. Report
    Khatrin. Gerhardus, et.al. “International measures of prevention, application, and economics of corrosion technologies study”, NACE Impact Report, pages 1–216, year 2006.
  2. Article in a Journal
    Rita Bacilar Figueira, “Hybrid sol-gel coatings for corrosion mitigation: a critical review.” Polymers, Volume 12, Number 689, 2020.
     U.S. Department of Health and Human Services, Public Health Service, Agency for Toxic Substances and Disease Registry Toxicological profile for Chromium, year 2008.
    USA Environ. Protection Agency, Wash. DC., Toxicological review of hexavalent chromium, year 1998.
    E. Almeida, et.al. , “Oxidizing Alternative Species to Chromium VI in Zinc Galvanised Steel Surface Treatment”, Surface and Coatings Technology, 106, 8-17, 1998.
     FH. Scholes, et.al. , “The role of hydrogen peroxide in the deposition of cerium-based conversion coatings”, Appl. Surf. Sci., 253:1770, 2006.
    X. Zhang, et.al. , “Comparison of the morphology and corrosion performance Cr(VI)- and Cr(III)-based conversion coatings on zinc”, Surf. Coat. Technol., 199:92, 2005.
    MN. Sathyanarayana, et.al. , “Role of promoters in improving adhesions of organic coatings to a substrate”, Prog. Org. Coat., 26 (2-4)275-313, 1995.
    Y. Dun, et.al. , “Microstructure and corrosion resistance of a fluorosilane modified silane-graphene film on 2024 aluminum alloy”, Appl. Surf. Sci. 437, 152–160, 2018.
     M. Naziruddin Khan, et.al. , “Influence of solvent on the physical and lasing properties of dye-doped sol–gel host”, J. Lumin., 128, 1767–1770, 2008.
     N.D. Johari, et.al. ,  “Comparison on the TiO2 crystalline phases deposited via dip and spin coating using green sol–gel route”, J. Mater. Res. Technol. 8, 2350–2358, 2019.
     L. Sopchenski, et.al. , M.G. Olivier, “Improvement of wear and corrosion protection of PEO on AA2024 via sol-gel sealing”, Surf. Coating. Technol. 417, 127195, 2021.
     C.A. Hernandez-Barrios, et.al. , “Effect of the catalyst concentration, the immersion time and the aging time on the morphology, composition and corrosion performance of TEOS-GPTMS sol-gel coatings deposited on the AZ31 magnesium alloy”, Surf. Coating. Technol. 325, 257–269, 2017.
     R. del Olmo, et.al. , Hybrid sol-gel coatings applied on anodized AA2024-T3 for active corrosion protection”, Surf. Coating. Technol. 419, 127251, 2021.
     A. Mazur, A. Szczurek, J.G. Chęcmanowski, B. Szczygieł, Corrosion resistance and bioactivity of SiO2-Y2O3 coatings deposited on 316L steel, Surf. Coating. Technol. 350, 502–510, 2018.
    K.A. Yasakau, et.al. , Influence of sol-gel process parameters on the protection properties of sol–gel coatings applied on AA2024, Surf. Coating. Technol. 246, 6–16, 2014.
    F.X. Perrin, F. Ziarelli, A. Dupuis, “Relation between the corrosion resistance and the chemical structure of hybrid sol-gel coatings with interlinked inorganic-organic network”, Prog. Org. Coating 141, 105532, 2020.
     M. Moradi-Haji Jafan, M.-R. Zamani-Meymian, R. Rahimi, M. Rabbani, “The effect of solvents and the thickness on structural, optical and electrical properties of ITO thin films prepared by a sol–gel spin-coating process”, J. Nanostruct. Chem. 4, 2014.
    R. Yahata, H. Kozuka, “Stress evolution of sol-gel-derived silica coatings during heating: the effects of the chain length of alcohols as solvents”, Thin Solid Films 517, 1983–1988, 2009.
     J.Y. Li, D.K. Wang, H.H. Tseng, M.Y. Wey, “Solvent effects on diffusion channel construction of organosilica membrane with excellent CO2 separation properties”, J. Membr. Sci. 618, 118758, 2021.
    C. Huck-Iriart, N. J. Morales, M. L. Herrera, and R. J. Candal, “Micro to mesoporous SiO2 xerogels: the effect of acid catalyst type in sol–gel process.”, Journal of Sol-Gel Science and Technology, 102(1), 197-207, 2022.
    C. J. Brinker, G. W. Scherer, “Sol–Gel Science: The Physics and Chemistry of Sol–Gel Processing.”, Academic Press, San Diego, 1990.
    L. L. Hench, J. K. West, “The Sol–Gel Process.” Chem. Rev., 90 33–72 1990.
     E. Alibakhshi, E. Ghasemi, M. Mahdavian, “The influence of surface modification of lithium zinc phosphate pigment on corrosion inhibition of mild steel and adhesion strength of epoxy coating.”, J. Sol-Gel Sci. Technol. 72, 359–368, 2014.
    A. Ahmadi, B. Ramezanzadeh, M. Mahdavian, “Hybrid silane coating reinforced with silanized graphene oxide nanosheets with improved corrosion protective performance.”, RSC Adv. 6, 54102–54112, 2016.
  3. Articles from Conference Proceedings (published)
    M. B. Gargari, R. Karimzadeh, and A. Eslamimanesh, “Effect of sol–gel catalyst on the microstructure of silica based xerogel films for eco-friendly anticorrosion films,” Civilica.com, Jul. 27, 2024. https://civilica.com/doc/2034974/ (accessed Nov. 26, 2024).
    M. B. Gargari, R. Karimzadeh, and A. Eslamimanesh, “Environmental friendly Sol-gel silica-based coatings via the Dip coating technique for enhanced corrosion protection of Carbon Steel and metal alloys,” Civilica.com, Jul. 27, 2024. https://en.civilica.com/doc/2034973/ (accessed Nov. 26, 2024).